Electrolyte of the solid oxide fuel cells deposited by atmospheric plasma spraying of 8 mol.% yttria (8YSZ), is not applicable in as sprayed condition. Optimization of the plasma spraying process parameters or application of feedstock powder, consisting of 8YSZ and 5wt.% alumina improves the problem of gas leakage through electrolyte layer, whereas provides no solution to the problem of electrodes short-circuiting. Infiltration of deposited electrolyte layer with a thin aqueous solution of nitrate precursors of 8YSZ for one time is a solution to high gas permeability; however three infiltration cycles are required to omit the risk of electrodes short circuiting thoroughly.
Issue Section:
Research Papers
References
1.
Gorte
, R. J.
, Vohs
, J. M.
, and McIntosh
, S.
, 2004, “Recent Developments on Anodes for Direct Fuel Utilization in SOFC,” Solid State Ionics
175
, pp. 1
–6
. 2.
White
, B. D.
, and Kesler
, O.
, 2008, “Implications of Electronic Short Circuiting in Plasma Sprayed Solid Oxide Fuel Cells on Electrode Performance Evaluation by Electrochemical Impedance Spectroscopy,” J. Power Sources
, 177
(1), pp. 104
–110
. 3.
Gitzhofer
, F.
, 2000 “Integrated Fabrication Processes for Solid Oxide Fuel Cells Using Thermal Plasma Spray Technology
,” MRS Bull.
, 25
, pp. 38
–42
. 4.
Hui
, R.
, Wang, Z., Kesler, O., Rose, L., Jankovic, J., Yick, S., Maric, R. and Ghosh, D., 2007, “Thermal Plasma Spraying for SOFCs: Applications, Potential Advantages, and Challenges,” J. Power Sources
, 170
(2), pp. 308
–323
. 5.
Xing
, Y.-Z.
, Li, C. X., Li, C. J., Long, H. G. and Xie, Y. X., 2008, “Microstructure Development of Plasma-Sprayed Yttria-Stabilized Zirconia and Its Effect on Electrical Conductivity
,” Solid State Ionics
179
(27), pp. 1483
–1485
. 6.
Brinkiene
, K.
and Kezelis, R., 2005, “Effect of Alumina Addition on the Microstructure of Plasma Sprayed YSZ,” J. Eur. Ceram. Soc.
, 25
(12), pp. 2181
–2184
. 7.
Li
, C.-J.
, Ning, X.-J. and Li, C.-X., 2005, “Effect of Densification Processes on the Properties of Plasma-Sprayed YSZ Electrolyte Coatings for Solid Oxide Fuel Cells,” Surface and Coatings Technology
, 190
(1), pp. 60
–64
. 8.
Khor
, K. A.
, K. A., Yu., L.-G, Chan, S. H. and Chen, X. G., 2003, “Densification of Plasma Sprayed YSZ Electrolytes by Spark Plasma Sintering (SPS),” J. Eur. Ceram. Soc.
, 23
(11), pp. 1855
–1863
. 9.
Zhang
, C.
, Zhang, G., Leparoux, S., Li, C.-X., Li, C.-J. and Coddet, C., 2008, “Microwave Sintering of Plasma-Sprayed Yttria Stabilized Zirconia Electrolyte Coating,” J. Eur. Ceram. Soc.
, 28
(13), pp. 2529
–2538
. 10.
Ide
, T.
, Namikawa
, T.
, Yamazaki
, Y.
, and Kagaku
, D.
, 1996, “Preparation of 8YSZ Thin Films on Porous LSM by Electron Beam Evaporation,” Denki. Kagaku, 64
, pp. 681
–683
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