Abstract

Pickering emulsion is a new type of stable emulsion made by ultrafine solid particles instead of traditional surfactants as stabilizers, which has received widespread attention in recent years. The preparation methods of stator-rotor homogenization, high-pressure homogenization, and ultrasonic emulsification were compared with others in this work. The main factors affecting the stability of Pickering emulsion are the surface humidity of the solid particles, the polarity of the oil phase, and the oil–water ratio. These factors could affect the nature of the solid particles, the preparation process of Pickering emulsion, and the external environment. Consequently, the long-term stability of Pickering emulsion is still a challenge. The tribological investigations of Pickering emulsion were summarized, and the multifunctional Pickering emulsion shows superior prospects for tribological applications. Moreover, the latest development of Pickering emulsion offers a new strategy for smart lubrication in the near future.

References

1.
Ali
,
A.
,
Yilmaz
,
E.
, and
Sjöö
,
M.
,
2015
, “
A Novel Technology for Personal Care Emulsions
,”
SOFW J.
,
141
, pp.
11
15
. www.sofw.com/de/hikashop-menu-for-categories-listing/product/397-sofw-journal-11-2015-english-print
2.
Ramsden
,
W.
,
1904
, “
Separation of Solids in the Surface-Layers of Solutions and ‘Suspensions’(Observations on Surface-Membranes, Bubbles, Emulsions, and Mechanical Coagulation)—Preliminary Account
,”
Proc. R. Soc. London
,
72
(
477–486
), pp.
156
164
.
3.
Chevalier
,
Y.
, and
Bolzinger
,
M. A.
,
2013
, “
Emulsions Stabilized With Solid Nanoparticles: Pickering Emulsions
,”
Colloids Surf., A
,
439
, pp.
23
34
.
4.
Pickering
,
S. U.
,
1907
, “
CXCVI.—Emulsions
,”
J. Chem. Soc. Trans.
,
91
, pp.
2001
2021
.
5.
Yan
,
N.
,
Gray
,
M.
, and
Masliyah
,
J.
,
2001
, “
On Water-in-Oil Emulsions Stabilized by Fine Solids
,”
Colloids Surf., A
,
193
(
1–3
), pp.
97
107
.
6.
Melle
,
S.
,
Lask
,
M.
, and
Fuller
,
G. G.
,
2005
, “
Pickering Emulsions With Controllable Stability
,”
Langmuir
,
21
(
6
), pp.
2158
2162
.
7.
Ganley
,
W. J.
, and
van Duijneveldt
,
J. S.
,
2016
, “
Steady-State Droplet Size in Montmorillonite Stabilised Emulsions
,”
Soft Matter
,
12
(
30
), pp.
6481
6489
.
8.
Binks
,
B. P.
, and
Lumsdon
,
S. O.
,
2001
, “
Pickering Emulsions Stabilized by Monodisperse Latex Particles: Effects of Particle Size
,”
Langmuir
,
17
(
15
), pp.
4540
4547
.
9.
Paunov
,
V. N.
,
Cayre
,
O. J.
,
Noble
,
P. F.
,
Stoyanov
,
S. D.
,
Velikov
,
K. P.
, and
Golding
,
M.
,
2007
, “
Emulsions Stabilised by Food Colloid Particles: Role of Particle Adsorption and Wettability at the Liquid Interface
,”
J. Colloid Interface Sci.
,
312
(
2
), pp.
381
389
.
10.
Capron
,
I.
, and
Cathala
,
B.
,
2013
, “
Surfactant-Free High Internal Phase Emulsions Stabilized by Cellulose Nanocrystals
,”
Biomacromolecules
,
14
(
2
), pp.
291
296
.
11.
Rayner
,
M.
,
Marku
,
D.
,
Eriksson
,
M.
,
Sjöö
,
M.
,
Dejmek
,
P.
, and
Wahlgren
,
M.
,
2014
, “
Biomass-Based Particles for the Formulation of Pickering Type Emulsions in Food and Topical Applications
,”
Colloids Surf., A
,
458
, pp.
48
62
.
12.
Aveyard
,
R.
,
Binks
,
B. P.
, and
Clint
,
J. H.
,
2003
, “
Emulsions Stabilised Solely by Colloidal Particles
,”
Adv. Colloid Interface Sci.
,
100–102
, pp.
503
546
.
13.
Schmitt
,
V.
,
Destribats
,
M.
, and
Backov
,
R.
,
2014
, “
Colloidal Particles as Liquid Dispersion Stabilizer: Pickering Emulsions and Materials Thereof
,”
C.R. Phys.
,
15
(
8–9
), pp.
761
774
.
14.
Nicolai
,
T.
, and
Murray
,
B.
,
2017
, “
Particle Stabilized Water in Water Emulsions
,”
Food Hydrocolloids
,
68
, pp.
157
163
.
15.
Binks
,
B. P.
, and
Tyowua
,
A. T.
,
2016
, “
Oil-in-Oil Emulsions Stabilised Solely by Solid Particles
,”
Soft Matter
,
12
(
3
), pp.
876
887
.
16.
Tyowua
,
A. T.
,
Yiase
,
S. G.
, and
Binks
,
B. P.
,
2017
, “
Double Oil-in-Oil-in-Oil Emulsions Stabilised Solely by Particles
,”
J. Colloid Interface Sci
,
488
, pp.
127
134
.
17.
Shi
,
A.
,
Feng
,
X.
,
Wang
,
Q.
, and
Adhikari
,
B.
,
2020
, “
Pickering and High Internal Phase Pickering Emulsions Stabilized by Protein-Based Particles: A Review of Synthesis, Application and Prospective
,”
Food Hydrocolloids
,
109
, pp.
106
117
.
18.
Berton-Carabin
,
C. C.
, and
Schroen
,
K.
,
2015
, “
Pickering Emulsions for Food Applications: Background, Trends, and Challenges
,”
Annu. Rev. Food Sci. Technol.
,
6
, pp.
263
297
.
19.
Marto
,
J.
,
Ascenso
,
A.
,
Simoes
,
S.
,
Almeida
,
A. J.
, and
Ribeiro
,
H. M.
,
2016
, “
Pickering Emulsions: Challenges and Opportunities in Topical Delivery
,”
Expert Opin. Drug Deliv.
,
13
(
8
), pp.
1093
1107
.
20.
Colver
,
P. J.
, and
Bon
,
S. A.
,
2007
, “
Cellular Polymer Monoliths Made via Pickering High Internal Phase Emulsions
,”
Chem. Mater.
,
19
(
7
), pp.
1537
1539
.
21.
Zhu
,
Y.
,
Wang
,
W.
,
Yu
,
H.
, and
Wang
,
A.
,
2020
, “
Preparation of Porous Adsorbent via Pickering Emulsion Template for Water Treatment: A Review
,”
J. Environ Sci.
,
88
, pp.
217
236
.
22.
Yang
,
H.
,
Li
,
J.
, and
Zeng
,
X.
,
2018
, “
Tribological Behavior of Nanocarbon Materials With Different Dimensions in Aqueous Systems
,”
Friction
,
8
(
1
), pp.
29
46
.
23.
Albert
,
C.
,
Beladjine
,
M.
,
Tsapis
,
N.
,
Fattal
,
E.
,
Agnely
,
F.
, and
Huang
,
N.
,
2019
, “
Pickering Emulsions: Preparation Processes, Key Parameters Governing Their Properties and Potential for Pharmaceutical Applications
,”
J. Controlled Release
,
309
, pp.
302
332
.
24.
Destribats
,
M.
,
Wolfs
,
M.
,
Pinaud
,
F.
,
Lapeyre
,
V.
,
Sellier
,
E.
,
Schmitt
,
V.
, and
Ravaine
,
V.
,
2013
, “
Pickering Emulsions Stabilized by Soft Microgels: Influence of the Emulsification Process on Particle Interfacial Organization and Emulsion Properties
,”
Langmuir
,
29
(
40
), pp.
12367
12374
.
25.
Thompson
,
K. L.
,
Armes
,
S. P.
, and
York
,
D. W.
,
2011
, “
Preparation of Pickering Emulsions and Colloidosomes With Relatively Narrow Size Distributions by Stirred Cell Membrane Emulsification
,”
Langmuir
,
27
(
6
), pp.
2357
2363
.
26.
Köhler
,
K.
,
Santana
,
A. S.
,
Braisch
,
B.
,
Preis
,
R.
, and
Schuchmann
,
H. P.
,
2010
, “
High Pressure Emulsification With Nano-particles as Stabilizing Agents
,”
Chem. Eng. Sci.
,
65
(
10
), pp.
2957
2964
.
27.
Sarker
,
M.
,
Tomczak
,
N.
, and
Lim
,
S.
,
2017
, “
Protein Nanocage as a pH-Switchable Pickering Emulsifier
,”
ACS Appl. Mater. Interfaces
,
9
(
12
), pp.
11193
11201
.
28.
Castel
,
V.
,
Rubiolo
,
A. C.
, and
Carrara
,
C. R.
,
2017
, “
Droplet Size Distribution, Rheological Behavior and Stability of Corn Oil Emulsions Stabilized by a Novel Hydrocolloid (Brea gum) Compared With Gum Arabic
,”
Food Hydrocolloids
,
63
, pp.
170
177
.
29.
Yuan
,
Q.
,
Cayre
,
O. J.
,
Manga
,
M.
,
Williams
,
R. A.
, and
Biggs
,
S.
,
2010
, “
Preparation of Particle-Stabilized Emulsions Using Membrane Emulsification
,”
Soft Matter
,
6
(
7
), pp.
1580
1588
.
30.
Yuan
,
Q.
,
Aryanti
,
N.
,
Gutiérrez
,
G.
,
Williams
,
R. A. J. I.
, and
Research
,
E. C.
,
2009
, “
Enhancing the Throughput of Membrane Emulsification Techniques to Manufacture Functional Particles
,”
Ind. Eng. Chem. Res.
,
48
(
19
), pp.
8872
8880
.
31.
Nakashima
,
T.
,
Shimizu
,
M.
, and
Kukizaki
,
M.
,
1992
, “
Membrane Emulsification by Microporous Glass
,”
Key Eng. Mater.
,
61–62
, pp.
513
516
.
32.
Xu
,
Q. Y.
,
Nakajima
,
M.
, and
Binks
,
B. P.
,
2005
, “
Preparation of Particle-Stabilized Oil-in-Water Emulsions With the Microchannel Emulsification Method
,”
Colloids Surf., A
,
262
(
1–3
), pp.
94
100
.
33.
Holtze
,
C.
,
2013
, “
Large-Scale Droplet Production in Microfluidic Devices—An Industrial Perspective
,”
J. Phys. D: Appl. Phys.
,
46
(
11
), p.
114008
.
34.
Maa
,
Y. F.
, and
Hsu
,
C.
,
1996
, “
Liquid-Liquid Emulsification by Rotor/Stator Homogenization
,”
J. Controlled Release
,
38
(
2–3
), pp.
219
228
.
35.
Kempin
,
M. V.
,
Kraume
,
M.
, and
Drews
,
A.
,
2020
, “
W/O Pickering Emulsion Preparation Using a Batch Rotor-Stator Mixer—Influence on Rheology, Drop Size Distribution and Filtration Behavior
,”
J. Colloid Interface Sci.
,
573
, pp.
135
149
.
36.
Stang
,
M.
,
Schuchmann
,
H.
, and
Schubert
,
H.
,
2001
, “
Emulsification in High-Pressure Homogenizers
,”
Eng. Life Sci.
,
1
(
4
), pp.
151
157
.
37.
Gupta
,
R.
, and
Rousseau
,
D.
,
2012
, “
Surface-Active Solid Lipid Nanoparticles as Pickering Stabilizers for Oil-in-Water Emulsions
,”
Food Funct.
,
3
(
3
), pp.
302
311
.
38.
Canselier
,
J. P.
,
Delmas
,
H.
,
Wilhelm
,
A. M.
, and
Abismaïl
,
B.
,
2002
, “
Ultrasound Emulsification—An Overview
,”
J. Dispersion Sci. Technol.
,
23
(
1–3
), pp.
333
349
.
39.
Kaltsa
,
O.
,
Gatsi
,
I.
,
Yanniotis
,
S.
, and
Mandala
,
I.
,
2014
, “
Influence of Ultrasonication Parameters on Physical Characteristics of Olive Oil Model Emulsions Containing Xanthan
,”
Food Bioprocess Technol.
,
7
(
7
), pp.
2038
2049
.
40.
Vladisavljević
,
G. T.
,
Kobayashi
,
I.
, and
Nakajima
,
M.
,
2012
, “
Production of Uniform Droplets Using Membrane, Microchannel and Microfluidic Emulsification Devices
,”
Microfluid. Nanofluid.
,
13
(
1
), pp.
151
178
.
41.
Sugiura
,
S.
,
Nakajima
,
M.
, and
Seki
,
M. J. L.
,
2002
, “
Prediction of Droplet Diameter for Microchannel Emulsification
,”
Langmuir
,
18
(
10
), pp.
3854
3859
.
42.
Priest
,
C.
,
Reid
,
M. D.
, and
Whitby
,
C. P.
,
2011
, “
Formation and Stability of Nanoparticle-Stabilised Oil-in-Water Emulsions in a Microfluidic Chip
,”
J. Colloid Interface Sci.
,
363
(
1
), pp.
301
306
.
43.
Binks
,
B. P.
, and
Lumsdon
,
S. O.
,
2000
, “
Effects of Oil Type and Aqueous Phase Composition on Oil–Water Mixtures Containing Particles of Intermediate Hydrophobicity
,”
Phys. Chem. Chem. Phys.
,
2
(
13
), pp.
2959
2967
.
44.
Binks
,
B. P.
,
2002
, “
Particles as Surfactants-Similarities and Differences
,”
Curr. Opin. Colloid Interface Sci.
,
7
(
1
), pp.
21
41
.
45.
Binks
,
B. P.
, and
Clint
,
J. H.
,
2002
, “
Solid Wettability From Surface Energy Components: Relevance to Pickering Emulsions
,”
Langmuir
,
18
(
4
), pp.
1270
1273
.
46.
Finkle
,
P.
,
Draper
,
H. D.
, and
Hildebrand
,
J. H.
,
1923
, “
The Theory of emulsification1
,”
J. Am. Chem. Soc.
,
45
(
12
), pp.
2780
2788
.
47.
Hórvölgyi
,
Z.
,
Németh
,
S.
, and
Fendler
,
J. H.
,
1996
, “
Monoparticulate Layers of Silanized Glass Spheres at the Water−Air Interface: Particle−Particle and Particle−Subphase Interactions
,”
Langmuir
,
12
(
4
), pp.
997
1004
.
48.
Horozov
,
T. S.
,
Aveyard
,
R.
,
Clint
,
J. H.
, and
Binks
,
B. P. J. L.
,
2003
, “
Order−Disorder Transition in Monolayers of Modified Monodisperse Silica Particles at the Octane−Water Interface
,”
Langmuir
,
19
(
7
), pp.
2822
2829
.
49.
Yan
,
N.
, and
Masliyah
,
J. H.
,
1996
, “
Effect of pH on Adsorption and Desorption of Clay Particles at Oil–Water Interface
,”
J. Colloid Interface Sci.
,
181
(
1
), pp.
20
27
.
50.
Yan
,
N.
,
Maham
,
Y.
,
Masliyah
,
J. H.
,
Gray
,
M. R.
, and
Mather
,
A. E.
,
2000
, “
Measurement of Contact Angles for Fumed Silica Nanospheres Using Enthalpy of Immersion Data
,”
J. Colloid Interface Sci.
,
228
(
1
), pp.
1
6
.
51.
Paunov
,
V. N.
,
2003
, “
Novel Method for Determining the Three-Phase Contact Angle of Colloid Particles Adsorbed at Air−Water and Oil−Water Interfaces
,”
Langmuir
,
19
(
19
), pp.
7970
7976
.
52.
Kaptay
,
G.
,
2006
, “
On the Equation of the Maximum Capillary Pressure Induced by Solid Particles to Stabilize Emulsions and Foams and on the Emulsion Stability Diagrams
,”
Colloids Surf., A
,
282–283
, pp.
387
401
.
53.
Yin
,
G.
,
Zheng
,
Z.
,
Wang
,
H.
, and
Du
,
Q.
,
2011
, “
Slightly Surface-Functionalized Polystyrene Microspheres Prepared via Pickering Emulsion Polymerization Using for Electrophoretic Displays
,”
J. Colloid Interface Sci.
,
361
(
2
), pp.
456
464
.
54.
Binks
,
B. P.
, and
Whitby
,
C. P.
,
2004
, “
Silica Particle-Stabilized Emulsions of Silicone Oil and Water: Aspects of Emulsification
,”
Langmuir
,
20
(
4
), pp.
1130
1137
.
55.
Levine
,
S.
,
Bowen
,
B. D.
, and
Partridge
,
S. J.
,
1989
, “
Stabilization of Emulsions by Fine Particles I. Partitioning of Particles Between Continuous Phase and Oil/Water Interface
,”
Colloids Surf.
,
38
(
2
), pp.
325
343
.
56.
Tambe
,
D. E.
, and
Sharma
,
M. M.
,
1994
, “
The Effect of Colloidal Particles on Fluid-Fluid Interfacial Properties and Emulsion Stability
,”
Adv. Colloid Interface Sci.
,
52
, pp.
1
63
.
57.
Tsabet
,
È
, and
Fradette
,
L.
,
2015
, “
Effect of the Properties of Oil, Particles, and Water on the Production of Pickering Emulsions
,”
Chem. Eng. Res. Des.
,
97
, pp.
9
17
.
58.
Tang
,
J.
,
Quinlan
,
P. J.
, and
Tam
,
K. C.
,
2015
, “
Stimuli-Responsive Pickering Emulsions: Recent Advances and Potential Applications
,”
Soft Matter
,
11
(
18
), pp.
3512
3529
.
59.
Amalvy
,
J. I.
,
Armes
,
S. P.
,
Binks
,
B. P.
,
Rodrigues
,
J. A.
, and
Unali
,
G. F.
,
2003
, “
Use of Sterically-Stabilised Polystyrene Latex Particles as a pH-Responsive Particulate Emulsifier to Prepare Surfactant-Free Oil-in-Water Emulsions
,”
Chem. Commun.
,
9
(
15
), pp.
1826
1827
.
60.
Vignati
,
E.
,
Piazza
,
R.
, and
Lockhart
,
T. P.
,
2003
, “
Pickering Emulsions: Interfacial Tension, Colloidal Layer Morphology, and Trapped-Particle Motion
,”
Langmuir
,
19
(
17
), pp.
6650
6656
.
61.
Fujii
,
S.
,
Okada
,
M.
, and
Furuzono
,
T.
,
2007
, “
Hydroxyapatite Nanoparticles as Stimulus-Responsive Particulate Emulsifiers and Building Block for Porous Materials
,”
J. Colloid Interface Sci.
,
315
(
1
), pp.
287
296
.
62.
Kalashnikova
,
I.
,
Bizot
,
H.
,
Bertoncini
,
P.
,
Cathala
,
B.
, and
Capron
,
I.
,
2013
, “
Cellulosic Nanorods of Various Aspect Ratios for Oil in Water Pickering Emulsions
,”
Soft Matter
,
9
(
3
), pp.
952
959
.
63.
San-Miguel
,
A.
, and
Behrens
,
S. H.
,
2012
, “
Influence of Nanoscale Particle Roughness on the Stability of Pickering Emulsions
,”
Langmuir
,
28
(
33
), pp.
12038
12043
.
64.
Pushpam
,
S. D.
,
Basavaraj
,
M. G.
, and
Mani
,
E.
,
2015
, “
Pickering Emulsions Stabilized by Oppositely Charged Colloids: Stability and Pattern Formation
,”
Phys. Rev. E.
,
92
(
5
), p.
052314
.
65.
Ridel
,
L.
,
Bolzinger
,
M. A.
,
Gilon-Delepine
,
N.
,
Dugas
,
P. Y.
, and
Chevalier
,
Y.
,
2016
, “
Pickering Emulsions Stabilized by Charged Nanoparticles
,”
Soft Matter
,
12
(
36
), pp.
7564
7576
.
66.
Yang
,
F.
,
Liu
,
S.
,
Xu
,
J.
,
Lan
,
Q.
,
Wei
,
F.
, and
Sun
,
D.
,
2006
, “
Pickering Emulsions Stabilized Solely by Layered Double Hydroxides Particles: The Effect of Salt on Emulsion Formation and Stability
,”
J. Colloid Interface Sci.
,
302
(
1
), pp.
159
169
.
67.
He
,
Y.
,
Wu
,
F.
,
Sun
,
X.
,
Li
,
R.
,
Guo
,
Y.
,
Li
,
C.
,
Zhang
,
L.
,
Xing
,
F.
,
Wang
,
W.
, and
Gao
,
J.
,
2013
, “
Factors That Affect Pickering Emulsions Stabilized by Graphene Oxide
,”
ACS Appl. Mater. Interfaces
,
5
(
11
), pp.
4843
4855
.
68.
Katepalli
,
H.
,
John
,
V. T.
,
Tripathi
,
A.
, and
Bose
,
A.
,
2017
, “
Microstructure and Rheology of Particle Stabilized Emulsions: Effects of Particle Shape and Inter-particle Interactions
,”
J. Colloid Interface Sci.
,
485
, pp.
11
17
.
69.
Yang
,
Z.
,
Guo
,
Z.
, and
Yuan
,
C.
,
2019
, “
Effects of MoS2 Microencapsulation on the Tribological Properties of a Composite Material in a Water-Lubricated Condition
,”
Wear
,
432–433
, p.
102919
.
70.
Li
,
H.
,
Chen
,
S.
,
Li
,
Z.
,
Feng
,
Y.
, and
Zhang
,
M.
,
2020
, “
Preparation of PU/GO Hybrid Wall Microcapsules and Their Self-lubricating Properties for Epoxy Composites
,”
Colloids Surf., A
,
596
, p.
124729
.
71.
Li
,
H.
,
Li
,
S.
,
Li
,
Z.
,
Zhu
,
Y.
, and
Wang
,
H.
,
2017
, “
Polysulfone/SiO2 Hybrid Shell Microcapsules Synthesized by the Combination of Pickering Emulsification and the Solvent Evaporation Technique and Their Application in Self-lubricating Composites
,”
Langmuir
,
33
(
49
), pp.
14149
14155
.
72.
Li
,
H.
,
Li
,
S.
,
Li
,
F.
,
Li
,
Z.
, and
Wang
,
H.
,
2018
, “
Fabrication of SiO2 Wrapped Polystyrene Microcapsules by Pickering Polymerization for Self-lubricating Coatings
,”
J. Colloid Interface Sci.
,
528
, pp.
92
99
.
73.
Li
,
H.
,
Ma
,
Y.
,
Cui
,
Y.
,
Li
,
Z.
, and
Wang
,
H.
,
2019
, “
Ultralow Tribological Properties of Polymer Composites Containing [BMIm]PF6-Loaded Multilayer Wall Microcapsule
,”
Macromol. Mater. Eng.
,
304
(
4
), p.
1800791
.
74.
Taheri
,
R.
,
Kosasih
,
B.
,
Zhu
,
H.
, and
Tieu
,
A. K.
,
2019
, “
Dual Effects of TiSiO4 Composite Nanoparticles on Dispersion Stability and Lubrication Performance of Vegetable Oil-in-Water Emulsions
,”
Lubr. Sci.
,
31
(
1–2
), pp.
21
39
.
75.
Xue
,
S.
,
Cen
,
Y.
,
Yang
,
H.
,
Honda
,
T.
,
Nakanishi
,
Y.
,
Zhang
,
L.
,
Zhang
,
B.
, and
Zeng
,
X.
,
2020
, “
The Enhanced Lubrication of Water-Based Cutting Fluid by Functionalized GO
,”
Tribol. Lett.
,
68
(
3
), pp.
1
14
.
76.
Wang
,
F.-F.
,
Tan
,
G.
,
Ding
,
H.
,
Liu
,
Z.
, and
Cheng
,
Z.-L.
,
2021
, “
Novel Fabrication for 2D MOFs-Based Oil-in-Water Lubricating Emulsion via the Self-assembly Interface
,”
Mater. Lett.
,
297
, p.
129981
.
77.
Li
,
H.
,
Xue
,
S.
,
Shang
,
Y.
,
Li
,
J.
, and
Zeng
,
X.
,
2020
, “
Research and Application Progress Based on the Interfacial Properties of Graphene Oxide
,”
Adv. Mater. Interfaces
,
7
(
21
), p.
2000881
.
78.
Yang
,
H.
,
Zhao
,
L.
,
Xue
,
S.
,
Deng
,
Z.
,
Li
,
J.
, and
Zeng
,
X.
,
2019
, “
Branch-Chain Length Modulated Graphene Oxides for Regulating the Physicochemical and Tribophysical Properties of Pickering Emulsions
,”
Colloids Surf., A
,
579
, p.
123703
.
79.
Wu
,
Y.
,
Zeng
,
X.
,
Ren
,
T.
,
de Vries
,
E.
, and
van der Heide
,
E.
,
2017
, “
The Emulsifying and Tribological Properties of Modified Graphene Oxide in Oil-in-Water Emulsion
,”
Tribol. Int.
,
105
, pp.
304
316
.
80.
Shao
,
M.
,
Li
,
S.
,
Duan
,
C.
,
Yang
,
Z.
,
Qu
,
C.
,
Zhang
,
Y.
,
Zhang
,
D.
,
Wang
,
C.
,
Wang
,
T.
, and
Wang
,
Q.
,
2018
, “
Cobweb-Like Structural Stimuli-Responsive Composite With Oil Warehouse and Transportation System for Oil Storage and Recyclable Smart-Lubrication
,”
ACS Appl. Mater. Inter.
,
10
(
48
), pp.
41699
41706
.
81.
Guo
,
Y.
,
Liu
,
G.
,
Li
,
G.
,
Zhao
,
F.
,
Zhang
,
L.
,
Guo
,
F.
, and
Zhang
,
G.
,
2020
, “
Solvent-Free Ionic Silica Nanofluids: Smart Lubrication Materials Exhibiting Remarkable Responsiveness to Weak Electrical Stimuli
,”
Chem. Eng. J.
,
383
, p.
123202
.
82.
Cui
,
J.
,
Mu
,
B.
,
Yang
,
B.
,
Cui
,
J.
,
Guo
,
J.
,
Tian
,
L.
, and
Wang
,
X.
,
2020
, “
Mesoporous Silica as Smart Lubrication Containers Applied to Self-lubricating Polyurethane Materials
,”
J. Appl. Polym. Sci.
,
138
(
1
), p.
49612
.
83.
Wang
,
Y.
,
Zhu
,
L.
,
Zhang
,
H.
,
Huang
,
H.
, and
Jiang
,
L.
,
2020
, “
Formulation of pH and Temperature Dual-Responsive Pickering Emulsion Stabilized by Chitosan-Based Microgel for Recyclable Biocatalysis
,”
Carbohydr. Polym.
,
241
, p.
116373
.
84.
Jiang
,
Q.
,
Li
,
S.
,
Du
,
L.
,
Liu
,
Y.
, and
Meng
,
Z.
,
2021
, “
Soft Kappa-Carrageenan Microgels Stabilized Pickering Emulsion Gels: Compact Interfacial Layer Construction and Particle-Dominated Emulsion Gelation
,”
J. Colloid Interface Sci.
,
602
, pp.
822
833
.
You do not currently have access to this content.